Master/mistress cadre punjab science

Syllabus of chemistry for master cadre

 Inorganic chemistry

(1) chemical periodicity
Modren periodic law And present form of the periodic tables, s, p, d and f block elements, periodic trends in properties of elements Atomic and ionic radii, ionisation enthalpy, electron gain enthalpy, valance, oxidation states and chemical reactivity.

(2)general principles and process of isolation of metals
Modes of occerence of elements in nature, minrals, ores, steps involved in extraction of metals - concentration, reduction( chemical and electrolytic methods) and refining with special reference to extraction of Al , Cu , Zn and iron ; thermodynamic and electrochemical principles involved in extraction of metals.

(3)hydrogen
Position of hydrogen in periodic table, isotopes, prepration, properties and uses of hydrogen, physical and chemical properties of  water and heavy water, structure , prepration, reaction amd uses of hydrogen peroxide, hydrogen as a fuel. 

(4) s block elements
Group-1 and group-2 elements introduction, electronic configuration, and general trends in physical and chemical properties of the first element of each group, diagonal relationships . Prepration of some important compounds - sodium carbonate and sodium hydroxide ; industrial use of lime , limestone , plaster of paris and cement ; biological significance of Na, K, Mg and Ca.

(5)p-block elements
Group13 to group18 elements, electronic configuration general trends in physical and chemical properties of elements across the periods and down the group ; unique behaviour of 1st element in each group. Prepration properties and uses of boron and aluminium chloride and alums, allotropes of carbon , catenation; Structure & properties of silicates chlorides and alums, allotropes of carbon, catenation; structure & properties of silicates and zeolites. Properties and uses of nitrogen and phosphorus; Allotrophic forms, structure and uses of ammonia, nitric acid, and PCl3, PCl5, structure of oxides of phosphorus. Prepration, properties , structures and uses of ozone ; allotropic forms of sulpher, sulphuric acid and structures of oxoacids of sulphur.

(6)d&f block elements
Position in periodic table, electronic configurtions of d - block elements, general properties of transition elements , the lanthanides and actinoids , some applications of d and f block elements. Prepration, properties and uses of K2Cr2O7, and K MnO4.

(7)Co-ordination compound and organometallic compound
Introduction to co-ordination conpound, werner's theory; ligands, co-ordination number, denticity, chelation;IUPAC nomenclature of mononuclear co-ordination compound, isomerism , bonding, valance bond approach anx basic ideas of crystal field theory, colour, and magnetic properties. Importance of co-ordination conpounds( in qualitative analysis , extraction of metals, and in biological system) . Organometallic compound sysnthesis, bonding and structure, and reactivity. Organometallics in homogenous catalysis ,cages and metal clusters.

(8)Environmental chemistry
Environmental pollution,- Atmospheric, water and soil, Atmospheric pollution Tropospheric and Stratospheric, Tropospheric pollutents: oxides of carbon, nitrogen and sulpher, hydrocarbons; their sources, harmful effects and prevention; green house effect and global warming; acid rain , particulate pollutants. Smoke, dust, smog, fumes, mist; their sources, harmful effects and prevention.
Stratospheric pollution - major pollutents such as , pathogens, organic wastes and chemical pollutents; their harmful effects and prevention. Soil pollution - Major pollutants such as : pesticides ( insecticides, herbicides and fungicides), their harmful effects and prevention. Strategies to control environmental pollution.

(9)nuclear chemistry
Nuclear reactions, fission and fusion, radio analytical techniques and activation analysis.

(10)analytical chemistry
Sepration techniques, spectroscopic electro and thermoanalytical methods.

(11)Bioinorganic chemistry
Photosystems ,porphyrins, metalloenzymes, oxygen transport, electron transfer reaction, nitrogen fixation.


(12) physical characterisation of inorganic compounds by IR, Raman, NMR, EPR, mossbauer, UV-NQR,MS, electron spectroscopy and microscopic techniques.


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